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Issue 1, 2005
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The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis

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Abstract

Synthetic entry has been achieved into high oxidation state Mn–Ca cluster chemistry with the preparation of [Mn13Ca2O10(OH)2(OMe)2(O2CPh)18(H2O)4]; the structure contains [Mn4CaO4] sub-units similar to that found in the photosynthetic water oxidizing complex.

Graphical abstract: The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis

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Publication details

The article was received on 07 Sep 2004, accepted on 11 Oct 2004, published on 25 Nov 2004 and first published online on 25 Nov 2004


Article type: Communication
DOI: 10.1039/B413680B
Citation: Chem. Commun., 2005, 54-56
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    The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis

    A. Mishra, W. Wernsdorfer, K. A. Abboud and G. Christou, Chem. Commun., 2005, 54
    DOI: 10.1039/B413680B

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