Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

Caterina S. Aricó; Liam R. Cox

doi:10.1039/B409832C

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Organic & Biomolecular Chemistry

Issue 18, 2004

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Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

Caterina S. Aricó and Liam R. Cox

Org. Biomol. Chem., 2004, 2, 2558-2562

DOI: 10.1039/B409832C
Received 30 Jun 2004, Accepted 30 Jul 2004
First published on the web 13 Aug 2004

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Grubbs' first-generation, Ru metathesis complex 3 catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.

Abstract from Methods in Organic Synthesis 2004

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Organic & Biomolecular Chemistry

Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

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