Accelerated asymmetric transfer hydrogenation of aromatic ketones in water

Xiaofeng Wu; Xiaoguang Li; William Hems; Frank King; Jianliang Xiao

doi:10.1039/B403627A

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Organic & Biomolecular Chemistry

Issue 13, 2004

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Accelerated asymmetric transfer hydrogenation of aromatic ketones in water

Xiaofeng Wu , Xiaoguang Li , William Hems , Frank King and Jianliang Xiao

Org. Biomol. Chem., 2004, 2, 1818-1821

DOI: 10.1039/B403627A
Received 10 Mar 2004, Accepted 14 May 2004
First published on the web 25 May 2004

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Asymmetric transfer hydrogenation of various simple aromatic ketones by the Ru-TsDPEN catalyst was shown to be feasible in aqueous HCOONa without calling for any catalyst modification, furnishing ee's of up to 95% and significantly faster rates than in the HCOOH–NEt₃ azeotrope.

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Xiaofeng Wu
Xiaoguang Li
William Hems
Frank King
Jianliang Xiao

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Organic & Biomolecular Chemistry

Accelerated asymmetric transfer hydrogenation of aromatic ketones in water

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