Issue 11, 2004
From the journal:

New Journal of Chemistry

Propeller-shaped chain and 2D grid coordination polymers with the host molecule cyclotriveratrylene and (CB9H5Br5)−

Ruksanna Ahmada  and  Michaele J. Hardie*a  

* Corresponding authors

a School of Chemistry, University of Leeds, Leeds, UK
E-mail: m.j.hardie@leeds.ac.uk
Fax: +44 113 343 6565
Tel: +44 113 343 6458

Abstract

The host molecule cyclotriveratrylene (CTV) forms coordination polymers with the Group 1 metals K+ and Rb+ and with the carbaborane (CB9H5Br5)− as the counter-anion. [K(CTV)2](CB9H5Br5)(CF3CH2OH)2 has a chain structure with an unusual propeller-shaped cross-section, while [Rb(CTV)(CB9H5Br5)(CH3CN)] has a two-dimensional grid structure of distorted hexagonal topology and is one of the few examples of a rubidium acetonitrile complex.

Graphical abstract: Propeller-shaped chain and 2D grid coordination polymers with the host molecule cyclotriveratrylene and (CB9H5Br5)−

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Article information

DOI
https://doi.org/10.1039/B405031B
Article type
Paper
Submitted
06 Apr 2004
Accepted
14 Jul 2004
First published
04 Oct 2004

New J. Chem., 2004,28, 1315-1319

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Propeller-shaped chain and 2D grid coordination polymers with the host molecule cyclotriveratrylene and (CB9H5Br5)−

R. Ahmad and M. J. Hardie, New J. Chem., 2004, 28, 1315 DOI: 10.1039/B405031B

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