The X-ray crystal structure of the complex [(triphos)Fe(μ,η4:η4-BH6)Fe(triphos)]+ in conjunction with spectroscopic data reveals a central unit formally described as BH63−; DFT calculations show why this ligand is stable for iron but not for the ruthenium analogue.
The article was received on 29 Jan 2004, accepted on 04 Feb 2004 and first published on 23 Feb 2004
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