Issue 10, 2004
From the journal:

Journal of Materials Chemistry

Synthesis and characterization of a novel open-framework nickel–zinc phosphite with intersecting three-dimensional 16-ring channels

Zhi-En Lin,a   Jie Zhang,a   Shou-Tian Zhenga  and  Guo-Yu Yang*ab  

* Corresponding authors

a Coordination and Hydrothermal Chemistry Group, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: ygy@fjirsm.ac.cn

b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, China

Abstract

A new inorganic–organic hybrid solid, Ni(DETA)(H2O)Zn2(HPO3)3 (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO4 and HPO3 polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni2(DETA)2(H2O)2O2 dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.

Graphical abstract: Synthesis and characterization of a novel open-framework nickel–zinc phosphite with intersecting three-dimensional 16-ring channels

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Article information

DOI
https://doi.org/10.1039/B402321H
Article type
Paper
Submitted
16 Feb 2004
Accepted
17 Mar 2004
First published
21 Apr 2004

J. Mater. Chem., 2004,14, 1652-1655

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Synthesis and characterization of a novel open-framework nickel–zinc phosphite with intersecting three-dimensional 16-ring channels

Z. Lin, J. Zhang, S. Zheng and G. Yang, J. Mater. Chem., 2004, 14, 1652 DOI: 10.1039/B402321H

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