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Issue 21, 2004
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Synthesis and magnetic behavior of the tetrahedral cage complex [(cyclen)4V4(CN)6]6+

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Abstract

Reaction of [(cyclen)V(CF3SO3)2](CF3SO3) with 4 equiv. of Et4N(CN) in DMF generates the seven-coordinate complex [(cyclen)V(CN)3], while a reaction employing just 1.5 equiv. produces a tetrahedral cage complex, [(cyclen)4V4(CN)6]6+, in which antiferromagnetic coupling leads to an S = 0 ground state.

Graphical abstract: Synthesis and magnetic behavior of the tetrahedral cage complex [(cyclen)4V4(CN)6]6+

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Publication details

The article was received on 19 Aug 2004, accepted on 22 Sep 2004 and first published on 01 Oct 2004


Article type: Communication
DOI: 10.1039/B412804D
Citation: Dalton Trans., 2004,0, 3434-3436
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    Synthesis and magnetic behavior of the tetrahedral cage complex [(cyclen)4V4(CN)6]6+

    I. S. Lee and J. R. Long, Dalton Trans., 2004, 0, 3434
    DOI: 10.1039/B412804D

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