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Issue 17, 2004
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Macropolyhedral boron-containing cluster chemistry. Cluster assembly about a molybdenum centre. Formation of the 19-vertex [(CO)2MoB16H15C2Ph2]− anion

Michael J. Carr,a  Andreas Frankena  and  John D. Kennedya 
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a The School of Chemistry of the University of Leeds, Leeds, UK

Abstract

Fusion of nine-vertex [1-Ph-nido-1-CB8H11] with [Mo(CH3CN)3(CO)3] in the presence of tetramethylnaphthalenediamine gives the nineteen-vertex macropolyhedral metallaborane anion [(CO)2MoB16H15C2Ph2]− with a molybdenum(VI) twelve-atom coordination sphere.

Graphical abstract: Macropolyhedral boron-containing cluster chemistry. Cluster assembly about a molybdenum centre. Formation of the 19-vertex [(CO)2MoB16H15C2Ph2]− anion

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Publication details

The article was received on 16 Jul 2004, accepted on 26 Jul 2004 and first published on 03 Aug 2004


Article type: Communication
DOI: 10.1039/B410873F
Citation: Dalton Trans., 2004,0, 2612-2613
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    Macropolyhedral boron-containing cluster chemistry. Cluster assembly about a molybdenum centre. Formation of the 19-vertex [(CO)2MoB16H15C2Ph2]− anion

    M. J. Carr, A. Franken and J. D. Kennedy, Dalton Trans., 2004, 0, 2612
    DOI: 10.1039/B410873F

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