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Issue 20, 2004
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Metal–oxygen–metal arrays in lamellar hybrid materials: Cobalt and manganese 4-cyclohexene-1,2-dicarboxylates

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Abstract

We have obtained three layered hybrid materials from the hydrothermal reaction of 4-cyclohexene-1,2-dicarboxylic acid with Co and Mn salts: Co(C8H8O4) [1], Mn(H2O)(C8H8O4) [2], and Mn4(H2O)(C8H8O4)4·0.3(H2O) [3]. The structures for all materials were solved by single-crystal XRD ([1] P[1 with combining macron], a = 4.805(2) Å, b = 6.650(3) Å, c = 12.960(6) Å, α = 98.285(7)°, β = 98.986(7)°, γ = 95.689(7)°, V = 401.6(3) Å3, R1 = 0.0438; [2] P21/c, a = 11.151(2) Å, b = 11.330(2) Å, c = 7.6560(15) Å, β = 108.813(3)° , V = 915.6(3) Å3, R1 = 0.0412; [3] P[1 with combining macron], a = 11.412(3) Å, b = 12.136(4) Å, c = 13.809(4) Å, α = 104.703(6)°, β = 103.207(6)°, γ = 92.468(5)°, V = 1790.6(9) Å3, R1 = 0.1056). While all three structures are two-dimensional overall, the metal–oxygen–metal dimensionality within the layers varies from isolated metal atoms in the case of [1] to 1D ribbons of vertex sharing MnO6 octahedra [2] and 2D arrays of edge- and vertex-sharing polyhedra in [3].

Graphical abstract: Metal–oxygen–metal arrays in lamellar hybrid materials: Cobalt and manganese 4-cyclohexene-1,2-dicarboxylates

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Publication details

The article was received on 01 Jun 2004, accepted on 21 Jul 2004 and first published on 10 Sep 2004


Article type: Paper
DOI: 10.1039/B408178A
Citation: Dalton Trans., 2004,0, 3365-3369
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    Metal–oxygen–metal arrays in lamellar hybrid materials: Cobalt and manganese 4-cyclohexene-1,2-dicarboxylates

    D. S. Kim, P. M. Forster, G. D. de Delgado, S. Park and A. K. Cheetham, Dalton Trans., 2004, 0, 3365
    DOI: 10.1039/B408178A

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