Jump to main content
Jump to site search

Issue 20, 2004
Previous Article Next Article

Metal–oxygen–metal arrays in lamellar hybrid materials: Cobalt and manganese 4-cyclohexene-1,2-dicarboxylates

Author affiliations

Abstract

We have obtained three layered hybrid materials from the hydrothermal reaction of 4-cyclohexene-1,2-dicarboxylic acid with Co and Mn salts: Co(C8H8O4) [1], Mn(H2O)(C8H8O4) [2], and Mn4(H2O)(C8H8O4)4·0.3(H2O) [3]. The structures for all materials were solved by single-crystal XRD ([1] P[1 with combining macron], a = 4.805(2) Å, b = 6.650(3) Å, c = 12.960(6) Å, α = 98.285(7)°, β = 98.986(7)°, γ = 95.689(7)°, V = 401.6(3) Å3, R1 = 0.0438; [2] P21/c, a = 11.151(2) Å, b = 11.330(2) Å, c = 7.6560(15) Å, β = 108.813(3)° , V = 915.6(3) Å3, R1 = 0.0412; [3] P[1 with combining macron], a = 11.412(3) Å, b = 12.136(4) Å, c = 13.809(4) Å, α = 104.703(6)°, β = 103.207(6)°, γ = 92.468(5)°, V = 1790.6(9) Å3, R1 = 0.1056). While all three structures are two-dimensional overall, the metal–oxygen–metal dimensionality within the layers varies from isolated metal atoms in the case of [1] to 1D ribbons of vertex sharing MnO6 octahedra [2] and 2D arrays of edge- and vertex-sharing polyhedra in [3].

Graphical abstract: Metal–oxygen–metal arrays in lamellar hybrid materials: Cobalt and manganese 4-cyclohexene-1,2-dicarboxylates

Back to tab navigation
Please wait while Download options loads

Publication details

The article was received on 01 Jun 2004, accepted on 21 Jul 2004 and first published on 10 Sep 2004


Article type: Paper
DOI: 10.1039/B408178A
Citation: Dalton Trans., 2004, 3365-3369
  •   Request permissions

    Metal–oxygen–metal arrays in lamellar hybrid materials: Cobalt and manganese 4-cyclohexene-1,2-dicarboxylates

    D. S. Kim, P. M. Forster, G. D. de Delgado, S. Park and A. K. Cheetham, Dalton Trans., 2004, 3365
    DOI: 10.1039/B408178A

Search articles by author