Well-defined indium(III)				N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

Jamie H. Cotgreave; David Colclough; Gabriele Kociok-Köhn; Giuseppe Ruggiero; Christopher G. Frost; Andrew S. Weller

doi:10.1039/B404179H

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Dalton Transactions

Issue 10, 2004

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)₃ catalyst

Jamie H. Cotgreave,^a David Colclough,^b Gabriele Kociok-Köhn,^a Giuseppe Ruggiero,^a Christopher G. Frost*^a and Andrew S. Weller*^a

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Department of Chemistry, University of Bath, Bath

GlaxoSmithKline, Old Powder Mills, Leigh, Nr Tonbridge, Kent
E-mail: c.g.frost@bath.ac.uk

Dalton Trans., 2004, 1519-1520

DOI: 10.1039/B404179H
Received 19 Mar 2004, Accepted 08 Apr 2004
First published online 16 Apr 2004

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Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe₃ results in (IMes)InMe₂Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe₂(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)₂ on addition of HOTf.

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Jamie H. Cotgreave
David Colclough
Gabriele Kociok-Köhn
Giuseppe Ruggiero
Christopher G. Frost
Andrew S. Weller

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Dalton Transactions

Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)₃ catalyst

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Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

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Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)₃ catalyst