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Issue 16, 2004
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Coordination polymer incorporating maleonitriledithiolate copper clusters: electrocrystallization synthesis and crystal structure of (NPr4)2[Cu(MeCN)]2[Cu8(i-mnt)6]·(MeCN)0.5·(THF)0.25

Sandrine Perruchas*a  and  Kamal Boubekeura 
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* Corresponding authors

a Institut des Matériaux Jean Rouxel, 2 rue de la Houssinière, BP32229, Nantes cedex 3, France

Abstract

(NPr4)2[CuI(MeCN)]2[CuI8(i-mnt)6]·(MeCN)0.5·(THF)0.25 is prepared by electrocrystallization of a solution of (NPr4)4[CuI8(i-mnt)6]; the crystal structure consists in bidimensional layers characterised by coordination of copper atoms by the cyano groups of the iso-maleonitriledithiolate ligand of the octa-copper cluster.

Graphical abstract: Coordination polymer incorporating maleonitriledithiolate copper clusters: electrocrystallization synthesis and crystal structure of (NPr4)2[Cu(MeCN)]2[Cu8(i-mnt)6]·(MeCN)0.5·(THF)0.25

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Publication details

The article was received on 04 Jun 2004, accepted on 08 Jul 2004 and first published on 19 Jul 2004


Article type: Communication
DOI: 10.1039/B408458F
Citation: Dalton Trans., 2004,0, 2394-2395
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    Coordination polymer incorporating maleonitriledithiolate copper clusters: electrocrystallization synthesis and crystal structure of (NPr4)2[Cu(MeCN)]2[Cu8(i-mnt)6]·(MeCN)0.5·(THF)0.25

    S. Perruchas and K. Boubekeur, Dalton Trans., 2004, 0, 2394
    DOI: 10.1039/B408458F

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