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Issue 12, 2004
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The formation, reactivity and interconversion of novel η1- and η3-triazacyclononane complexes of rhodium(I) and rhodium(III)

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Abstract

We have successfully synthesised and characterised a number of η1- and η3-triazacyclononane RhI and RhIII derivatives. By using different reaction conditions, we have been able to convert one of the η1-triazacyclononane complexes to an η3-derivative. Also, we have observed a rare example of an addition of an organic fragment to a metal bound ligand to form a quaternary carbon centre.

Graphical abstract: The formation, reactivity and interconversion of novel η1- and η3-triazacyclononane complexes of rhodium(i) and rhodium(iii)

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Publication details

The article was received on 09 Feb 2004, accepted on 07 May 2004 and first published on 21 May 2004


Article type: Paper
DOI: 10.1039/B401877J
Citation: Dalton Trans., 2004,0, 1841-1845
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    The formation, reactivity and interconversion of novel η1- and η3-triazacyclononane complexes of rhodium(I) and rhodium(III)

    A. L. Gott, P. C. McGowan and C. N. Temple, Dalton Trans., 2004, 0, 1841
    DOI: 10.1039/B401877J

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