Vibrational dynamics of SCCl2 from the zero point to the first dissociation limit†
Abstract
Over one thousand
←
vibronic transitions of the SC35Cl2 and SC35Cl37Cl isotopomers, originating from eight
state vibrational levels, have been measured by dispersed
state potential surface and transition dipole surface, also reproduces the spectral intensities of the ν1–ν4 polyads up to E/h
= 240 THz. SCCl2 is an excellent model system for intramolecular vibrational redistribution (IVR) among skeletal vibrations ranging from isolated resonances to extensively mixed quantum states. The newly extended