Issue 6, 2004
From the journal:

Physical Chemistry Chemical Physics

Static permittivity of water revisited: ε in the electric field above 108 V m−1 and in the temperature range 273 ≤ T ≤ 373 K

I. Danielewicz-Ferchmina  and  A. R. Ferchmin*b  

* Corresponding authors

a Faculty of Physics, A. Mickiewicz University, Umultowska 85, PL-61-614 Poznań, Poland

b Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, PL-60-179 Poznań, Poland
E-mail: arfer@ifmpan.poznan.pl

Abstract

Calculations are presented of the permittivity of water residing in conditions encountered in hydration shells. The present approach is applicable to water in high electric fields and in the whole range of temperature where it is liquid. Possible applications to various systems are mentioned. Static permittivity of aqueous solutions of exemplary salts is calculated and its comparison with experiment discussed in some detail.

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Article information

DOI
https://doi.org/10.1039/B314337F
Article type
Paper
Submitted
07 Nov 2003
Accepted
22 Jan 2004
First published
19 Feb 2004

Phys. Chem. Chem. Phys., 2004,6, 1332-1339

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Static permittivity of water revisited: ε in the electric field above 108 V m−1 and in the temperature range 273 ≤ T ≤ 373 K

I. Danielewicz-Ferchmin and A. R. Ferchmin, Phys. Chem. Chem. Phys., 2004, 6, 1332 DOI: 10.1039/B314337F

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