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Issue 51, 2004

Molecular paneling of rac-1,1′-bi-2-naphthol/∼ate (BINOL/BINOLAT): hydrogen-bonded assembly of [M(NH3)4 or 6]2+ complexes (M = Ni, Zn, Cd) in cavities of {[BINOLAT]2−(BINOL)2}-strands

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Abstract

The naphthyl-paneled cavities in the {[BINOLAT]2−(BINOL)2}-host strands in the structures of [M(NH3)n]2+[BINOLAT]2−(BINOL)2 accommodate the [M(NH3)n]2+-guest cation through second-sphere N–H⋯O hydrogen bonding irrespective of the size (M = Ni or Cd, n= 6) or coordination polyhedron (tetrahedron for M = Zn, n= 4 or octahedron for M = Ni, Cd).

Graphical abstract: Molecular paneling of rac-1,1′-bi-2-naphthol/∼ate (BINOL/BINOLAT): hydrogen-bonded assembly of [M(NH3)4 or 6]2+ complexes (M = Ni, Zn, Cd) in cavities of {[BINOLAT]2−(BINOL)2}-strands

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Publication details

The article was received on 16 Jul 2004, accepted on 25 Aug 2004 and first published on 07 Sep 2004


Article type: Communication
DOI: 10.1039/B410933C
Citation: CrystEngComm, 2004,6, 293-297
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    Molecular paneling of rac-1,1′-bi-2-naphthol/∼ate (BINOL/BINOLAT): hydrogen-bonded assembly of [M(NH3)4 or 6]2+ complexes (M = Ni, Zn, Cd) in cavities of {[BINOLAT]2−(BINOL)2}-strands

    B. Paul, C. Näther, B. Walfort, K. M. Fromm, B. Zimmermann, H. Lang and C. Janiak, CrystEngComm, 2004, 6, 293
    DOI: 10.1039/B410933C

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