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Issue 22, 2004
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Nitrile oxide cycloadditions in supercritical carbon dioxide

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Abstract

The regioselectivity of dipolar cycloadditions of mesitonitrile oxide to various dipolarophiles in supercritical carbon dioxide can be tuned by changes in density, the magnesium bromide-mediated cycloaddition to pent-1-en-3-ol proceeding with higher stereoselectivity than in most conventional solvents.

Graphical abstract: Nitrile oxide cycloadditions in supercritical carbon dioxide

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Publication details

The article was received on 04 Nov 2003, accepted on 05 Aug 2004 and first published on 05 Oct 2004


Article type: Communication
DOI: 10.1039/B411561A
Citation: Chem. Commun., 2004,0, 2622-2623
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    Nitrile oxide cycloadditions in supercritical carbon dioxide

    C. K. Y. Lee, A. B. Holmes, B. Al-Duri, G. A. Leeke, R. C. D. Santos and J. P. K. Seville, Chem. Commun., 2004, 0, 2622
    DOI: 10.1039/B411561A

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