Through a 2e- oxidation-reduction cycle, phenylselenides catalytically activate N-chlorosuccinimide toward electrophilic reactions with ketones, resulting in α-haloketones.
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Selenocatalytic α-halogenation
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Department of Chemistry, University of Kansas, 1251 Wescoe Hall Dr., Lawrence, USA
E-mail: tunge@ku.edu
E-mail: tunge@ku.edu
Chem. Commun., 2004, 2694-2695
DOI: 10.1039/B410576A
Received 18 Jul 2004, Accepted 15 Sep 2004
First published online 07 Oct 2004
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Supplementary Info
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1H and 13C NMR spectra of all compounds
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