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Issue 20, 2004
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Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl

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Abstract

The reaction of various iodophenols with MeMgCl in presence of LiCl followed by the addition of i-PrMgCl provides the corresponding magnesiated magnesium phenolates as THF soluble reagents; this approach can be extended to heterocyclic compounds bearing a hydroxy group like pyridines and quinolines.

Graphical abstract: Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl

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Publication details

The article was received on 25 Jun 2004, accepted on 26 Jul 2004 and first published on 26 Aug 2004


Article type: Communication
DOI: 10.1039/B409664A
Citation: Chem. Commun., 2004,0, 2288-2289
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    Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl

    F. Kopp, A. Krasovskiy and P. Knochel, Chem. Commun., 2004, 0, 2288
    DOI: 10.1039/B409664A

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