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Issue 19, 2004
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Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes

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Abstract

Reversible geometry reorganisations are demonstrated by cis-3,5-diamino-trans-hydroxycyclohexane (cis,trans-DAHC) copper(II) fluoride complexes, with the concentration of water in the mother liquor controlling interconversion between blue crystals of 5-coordinate syn-[Cu(DAHC)2F](F)·2CH3OH·H2O and red crystals of 4-coordinate anti-[Cu(DAHC)2](F)2·2H2O.

Graphical abstract: Secondary coordination sphere controlled reversible geometry reorganisations in copper(ii) complexes

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Publication details

The article was received on 13 May 2004, accepted on 12 Jul 2004 and first published on 20 Aug 2004


Article type: Communication
DOI: 10.1039/B407229D
Citation: Chem. Commun., 2004,0, 2156-2157
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    Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes

    J. Fielden, D. Long and L. Cronin, Chem. Commun., 2004, 0, 2156
    DOI: 10.1039/B407229D

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