Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

Caleb M. May; Stephen J. Archibald; Adam J. Bridgeman; Christopher J. Empson; Timothy J. Hubin

doi:10.1039/B405358C

Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

Caleb M. May,^a Stephen J. Archibald,^b Adam J. Bridgeman,^b Christopher J. Empson^b and Timothy J. Hubin*^a

* Corresponding authors

^a Department of Natural Science, McPherson College, McPherson, USA 67460
E-mail: hubint@mcpherson.edu
Fax: (+1) 620 241-8443
Tel: (+1) 620 241-3568

^b Department of Chemistry, University of Hull, Cottingham Road, Kingston upon Hull, UK

Abstract

An unusual copper(II) complex of a highly rigid and bulky ligand (a macrocycle–glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.

Supplementary files

Publication details

The article was received on 13 Apr 2004, accepted on 24 May 2004 and first published on 07 Jul 2004

Article type: Communication

DOI: 10.1039/B405358C

Citation: Chem. Commun., 2004,0, 1880-1881

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Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

C. M. May, S. J. Archibald, A. J. Bridgeman, C. J. Empson and T. J. Hubin, Chem. Commun., 2004, 0, 1880
DOI: 10.1039/B405358C
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Chemical Communications

Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

Abstract

Supplementary files

Publication details

Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

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