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Issue 10, 2004
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A concise synthesis of a rigid isomannide-based diphosphine ligand and structural characterisation of an alkoxyphosphonium intermediate

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Abstract

The synthesis of the novel C2-symmetric diphosphine 1,4:3,6-dianhydro-2,5-bis(diphenylphosphino)-D-mannitol (ddppm) from D-isomannide is reported and its performance in asymmetric hydrogenations discussed.

Graphical abstract: A concise synthesis of a rigid isomannide-based diphosphine ligand and structural characterisation of an alkoxyphosphonium intermediate

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Publication details

The article was received on 29 Jan 2004, accepted on 06 Apr 2004 and first published on 27 Apr 2004


Article type: Communication
DOI: 10.1039/B401301H
Citation: Chem. Commun., 2004,0, 1236-1237
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    A concise synthesis of a rigid isomannide-based diphosphine ligand and structural characterisation of an alkoxyphosphonium intermediate

    C. Carcedo, A. Dervisi, I. A. Fallis, L. Ooi and K. M. A. Malik, Chem. Commun., 2004, 0, 1236
    DOI: 10.1039/B401301H

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