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Issue 6, 2004
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Kinetic resolution of chiral aminoalkenes via asymmetric hydroamination/cyclisation using binaphtholate yttrium complexes

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Abstract

Chiral binaphtholate yttrium aryl complexes are highly active and enantioselective catalysts for the asymmetric hydroamination of aminoalkenes, as well as the kinetic resolution of α-substituted 1-aminopent-4-enes to give trans-2,5-disubstituted pyrrolidines with good enantiomeric excess and high krel.

Graphical abstract: Kinetic resolution of chiral aminoalkenes via asymmetric hydroamination/cyclisation using binaphtholate yttrium complexes

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Publication details

The article was received on 11 Dec 2003, accepted on 26 Jan 2004 and first published on 20 Feb 2004


Article type: Communication
DOI: 10.1039/B316096C
Citation: Chem. Commun., 2004,0, 730-731
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    Kinetic resolution of chiral aminoalkenes via asymmetric hydroamination/cyclisation using binaphtholate yttrium complexes

    D. V. Gribkov and K. C. Hultzsch, Chem. Commun., 2004, 0, 730
    DOI: 10.1039/B316096C

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