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Issue 4, 2004
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A novel synthesis of chiral rotaxanes via covalent bond formation

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Abstract

Chiral rotaxanes composed of the asymmetric crownophane incorporating two hydroxy groups as a rotor moiety and the asymmetric axis were effectively synthesized via covalent bond formation, i.e. tandem Claisen rearrangement, esterification, and aminolysis.

Graphical abstract: A novel synthesis of chiral rotaxanes via covalent bond formation

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Publication details

The article was received on 14 Nov 2003, accepted on 07 Jan 2004 and first published on 28 Jan 2004


Article type: Communication
DOI: 10.1039/B314744D
Citation: Chem. Commun., 2004, 466-467
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    A novel synthesis of chiral rotaxanes via covalent bond formation

    N. Kameta, K. Hiratani and Y. Nagawa, Chem. Commun., 2004, 466
    DOI: 10.1039/B314744D

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