Issue 5, 2004
From the journal:

Chemical Communications

Cooperative C–F⋯Si interaction in optically active helical polysilanes†

Sun-Young Kim,a   Anubhav Saxena,bc   Giseop Kwak,b   Michiya Fujiki*bc  and  Yusuke Kawakamia  

* Corresponding authors

a Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Tatsunokuchi, Ishikawa 923-1292, Japan
E-mail: kawakami@jaist.ac.jp
Fax: +81 761 51 1635
Tel: +81 761 51 1632

b Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0101, Japan
E-mail: fujikim@ms.aist-nara.ac.jp
Fax: +81 743 72 6049
Tel: +81 743 72 6040

c CREST-JST, 4-1-8 Hon-Cho, Kawaguchi, Saitama 332-0012, Japan

Abstract

Cooperative amplification of the C–F⋯Si weak interaction between side chains and the main chain was found to afford rigid rodlike helical polysilanes with a preferential screw sense.

Graphical abstract: Cooperative C–F⋯Si interaction in optically active helical polysilanes

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Article information

DOI
https://doi.org/10.1039/B314723A
Article type
Communication
Submitted
14 Nov 2003
Accepted
24 Dec 2003
First published
27 Jan 2004

Chem. Commun., 2004, 538-539

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Cooperative C–F⋯Si interaction in optically active helical polysilanes

S. Kim, A. Saxena, G. Kwak, M. Fujiki and Y. Kawakami, Chem. Commun., 2004, 538 DOI: 10.1039/B314723A

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