Issue 9, 2004

An iterative approach to novel polyaminesvia nucleophilic ring-opening of aziridinium ions with β-amino alcohols

Abstract

An iterative procedure for the synthesis of a novel class of synthetic polyamines has been developed, utilising the regioselective ring-opening of aziridinium ion intermediates; facile N-allyl deprotection of intermediate polyamines allows the rapid construction of high molecular weight, stereochemically defined compounds in a convergent manner.

Graphical abstract: An iterative approach to novel polyamines via nucleophilic ring-opening of aziridinium ions with β-amino alcohols

Supplementary files

Article information

Article type
Communication
Submitted
02 Feb 2004
Accepted
09 Mar 2004
First published
01 Apr 2004

Chem. Commun., 2004, 1080-1081

An iterative approach to novel polyamines via nucleophilic ring-opening of aziridinium ions with β-amino alcohols

C. McKay, R. J. Wilson and C. M. Rayner, Chem. Commun., 2004, 1080 DOI: 10.1039/B401447B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements