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Issue 7, 2004
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On/off regulation of catalysis by allosteric control of metal complex nuclearity

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Abstract

The nature of the allosteric metal ion M (Pd2+ or Pt2+) in complexes ML of a polytopic ligand controls uptake of additional Cu2+ ions; while [Cu2Pd(L-4H)]2+ is a highly active catalyst for phosphodiester cleavage, [CuPt(L-4H)] is inactive.

Graphical abstract: On/off regulation of catalysis by allosteric control of metal complex nuclearity

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Publication details

The article was received on 11 Dec 2003, accepted on 30 Jan 2004 and first published on 04 Mar 2004


Article type: Communication
DOI: 10.1039/B316225G
Citation: Chem. Commun., 2004,0, 880-881
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    On/off regulation of catalysis by allosteric control of metal complex nuclearity

    L. Kovbasyuk, H. Pritzkow, R. Krämer and I. O. Fritsky, Chem. Commun., 2004, 0, 880
    DOI: 10.1039/B316225G

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