Issue 3, 2004
From the journal:

Chemical Communications

Fast, long-range electron-transfer reactions of a ‘blue’ copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer

Fraser A. Armstrong,a   Nicola L. Barlow,a   Paul L. Burn,b   Kevin R. Hoke,a   Lars J. C. Jeuken,†a   Catherine Shentona  and  Graham R. Websterb  

a Inorganic Chemistry Laboratory, Oxford University, South Parks Road, Oxford, England

b The Dyson Perrins Laboratory, Oxford University, South Parks Road, Oxford University, England

Abstract

A self-assembled monolayer (SAM), formed by the insitu saponification of a stilbenyl thioacetate on a gold electrode, yields fast electron transfer (ET) (the exchange rate at zero driving force exceeds 1600 s−1) with adsorbed molecules of the ‘blue’ copper protein, azurin, over a distance exceeding 15 Å.

Graphical abstract: Fast, long-range electron-transfer reactions of a ‘blue’ copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer

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Article information

DOI
https://doi.org/10.1039/B312936E
Article type
Communication
Submitted
15 Oct 2003
Accepted
20 Nov 2003
First published
07 Jan 2004

Chem. Commun., 2004, 316-317

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Fast, long-range electron-transfer reactions of a ‘blue’ copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer

F. A. Armstrong, N. L. Barlow, P. L. Burn, K. R. Hoke, L. J. C. Jeuken, C. Shenton and G. R. Webster, Chem. Commun., 2004, 316 DOI: 10.1039/B312936E

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