Jump to main content
Jump to site search

Issue 4, 2003
Previous Article Next Article

Kinetics of hydrolysis of 1-benzoyl-1,2,4-triazole in aqueous solution as a function of temperature near the temperature of maximum density, and the isochoric controversy

Author affiliations

Abstract

At temperatures above and below the temperature of maximum density, TMD, for water at ambient pressure, pairs of temperatures exist at which the molar volumes of water are equal. First-order rate constants for the pH-independent hydrolysis of 1-benzoyl-1,2,4-triazole in aqueous solution at pairs of such isochoric temperatures show no unique features. Taken together with previously published kinetic data for the hydrolysis of a range of simple organic solutes in both water and D2O near their respective TMDs, we conclude that special significance in the context of rates of chemical reactions in aqueous solutions should not be attached to the isochoric condition.

Graphical abstract: Kinetics of hydrolysis of 1-benzoyl-1,2,4-triazole in aqueous solution as a function of temperature near the temperature of maximum density, and the isochoric controversy

Back to tab navigation

Publication details

The article was received on 22 Oct 2002, accepted on 20 Dec 2002 and first published on 28 Jan 2003


Article type: Paper
DOI: 10.1039/B210246C
Citation: Org. Biomol. Chem., 2003,1, 720-723
  •   Request permissions

    Kinetics of hydrolysis of 1-benzoyl-1,2,4-triazole in aqueous solution as a function of temperature near the temperature of maximum density, and the isochoric controversy

    M. J. Blandamer, N. J. Buurma, J. B. F. N. Engberts and J. C. R. Reis, Org. Biomol. Chem., 2003, 1, 720
    DOI: 10.1039/B210246C

Search articles by author

Spotlight

Advertisements