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Issue 2, 2003
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Synthesis and evaluation of N,S-compounds as chiral ligands for transfer hydrogenation of acetophenone

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Abstract

New nitrogen- and sulfur-containing compounds, bicyclic and monocyclic, were prepared and evaluated as ligands in the transfer hydrogenation of acetophenone. Utilising [Ir(COD)Cl]2 as metal precursor the best result, 80% ee, was obtained using a bicyclic sulfoxide ligand.

Graphical abstract: Synthesis and evaluation of N,S-compounds as chiral ligands for transfer hydrogenation of acetophenone

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Publication details

The article was received on 11 Sep 2002, accepted on 05 Nov 2002 and first published on 09 Dec 2002


Article type: Paper
DOI: 10.1039/B208907F
Citation: Org. Biomol. Chem., 2003,1, 358-366
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    Synthesis and evaluation of N,S-compounds as chiral ligands for transfer hydrogenation of acetophenone

    J. K. Ekegren, P. Roth, K. Källström, T. Tarnai and P. G. Andersson, Org. Biomol. Chem., 2003, 1, 358
    DOI: 10.1039/B208907F

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