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Issue 3, 2003
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Three-component coupling reactions in ionic liquids: a facile synthesis of α-aminonitriles

Jhillu S. Yadav,*a  Basi. V. S. Reddy,a  B. Eshwaraiah,a  Mende. Srinivasa  and  P. Vishnumurthya 
Author affiliations

* Corresponding authors

a Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad, India
E-mail: yadav@iict.ap.nic.in
Fax: 91-40-7160512

Abstract

Aryl imines, derived in situ from aldehydes and amines, smoothly undergo addition with trimethylsilyl cyanide in 1-butyl-3-methylimidazolium tetrafluoroborate or 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquids under mild and neutral reaction conditions to afford the corresponding α-aminonitriles in excellent yields. The ionic liquids can be recycled in five to six runs without any apparent loss of activity.

Graphical abstract: Three-component coupling reactions in ionic liquids: a facile synthesis of α-aminonitriles

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Publication details

The article was received on 09 Sep 2002, accepted on 10 Dec 2002 and first published on 14 Jan 2003


Article type: Letter
DOI: 10.1039/B208844B
Citation: New J. Chem., 2003,27, 462-465
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    Three-component coupling reactions in ionic liquids: a facile synthesis of α-aminonitriles

    J. S. Yadav, Basi. V. S. Reddy, B. Eshwaraiah, Mende. Srinivas and P. Vishnumurthy, New J. Chem., 2003, 27, 462
    DOI: 10.1039/B208844B

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