Issue 5, 2003

A non-interpenetrating 2D coordination polymer from a (CH2)8 spacer-based highly flexible linear ligand and AgCF3CO2

Abstract

Reaction of a (CH2)8 spacer-based ligand, 1,8-bis(8-thioquinolyl)octane (C8TQ), with AgCF3CO2 affords a designed non-interpenetrating 2D brick-wall coordination polymer [Ag2(C8TQ)(CF3CO2)2]n, composed of thio-bridged helical chains racemically aligned and further connected by the (CH2)8 spacers, while weak F⋯F interactions between ligated CF3CO2 fabricate the 3D supramolecular architecture.

Graphical abstract: A non-interpenetrating 2D coordination polymer from a (CH2)8 spacer-based highly flexible linear ligand and AgCF3CO2

Supplementary files

Article information

Article type
Letter
Submitted
13 Feb 2003
Accepted
13 Mar 2003
First published
11 Apr 2003

New J. Chem., 2003,27, 790-792

A non-interpenetrating 2D coordination polymer from a (CH2)8 spacer-based highly flexible linear ligand and AgCF3CO2

C. Chen, C. Su, Y. Cai, H. Zhang, A. Xu and B. Kang, New J. Chem., 2003, 27, 790 DOI: 10.1039/B301777J

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