Issue 1, 2003
From the journal:

New Journal of Chemistry

Novel zigzag 1D coordination polymer from copper(ii) chloride and N,N′-{2,4-di[(di-pyridin-2-yl)amine]-1,3,5-triazine}ethylenediamine exhibiting ferromagnetic interactions

Paul de Hoog,a   Patrick Gamez,*a   Olivier Roubeau,a   Martin Lutz,b   Willem L. Driessen,a   Anthony L. Spekb  and  Jan Reedijk*a  

* Corresponding authors

a Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, Leiden, The Netherlands
E-mail: p.gamez@chem.leidenuniv.nl; reedijk@chem.leidenuniv.nl
Fax: +31 71 527 4671

b Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, Utrecht, The Netherlands

Abstract

Copper(II) chloride reacts with the polydentate 1,3,5-triazine containing ligand opytrizediam in methanol–THF to form a unique infinite zigzag coordination polymer in which trinuclear copper complexes are bridged by chloride anions, giving rise to five-coordinated ferromagnetically coupled copper pseudo-dimers.

Graphical abstract: Novel zigzag 1D coordination polymer from copper(ii) chloride and N,N′-{2,4-di[(di-pyridin-2-yl)amine]-1,3,5-triazine}ethylenediamine exhibiting ferromagnetic interactions

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Article information

DOI
https://doi.org/10.1039/B206344A
Article type
Letter
Submitted
02 Jul 2002
Accepted
05 Aug 2002
First published
23 Sep 2002

New J. Chem., 2003,27, 18-21

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Novel zigzag 1D coordination polymer from copper(II) chloride and N,N′-{2,4-di[(di-pyridin-2-yl)amine]-1,3,5-triazine}ethylenediamine exhibiting ferromagnetic interactions

P. de Hoog, P. Gamez, O. Roubeau, M. Lutz, W. L. Driessen, A. L. Spek and J. Reedijk, New J. Chem., 2003, 27, 18 DOI: 10.1039/B206344A

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