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Issue 3, 2003
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Spontaneous resolution of a non-degenerate donor–acceptor [2]catenane

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Abstract

The incorporation of a 3,5-bis(methylene)-1H-1,2,4-triazole unit into the macrocyclic polyether component of a donor–acceptor [2]catenane induces selectivity in the isomerization processes operating within the molecule, since it exists both in solution and in the solid state as only one of two possible translational isomers, and, upon crystallisation, undergoes spontaneous resolution under racemizing conditions.

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Publication details

The article was received on 30 May 2003


Article type: Communication
Citation: Mendeleev Commun., 2003,13, 100-102

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