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Issue 2, 2003
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Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(III) ligands in supercritical CO2 and CH2Cl2

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Abstract

Four chiral perfluoroalkylated monodentate phosphorus(III) ligands have been prepared and characterised. These ligands have been evaluated in the rhodium-catalysed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2 (scCO2) and compared with the parent, non-perfluoroalkylated, catalyst systems.

Graphical abstract: Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2

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Publication details

The article was received on 11 Dec 2002 and first published on 27 Mar 2003


Article type: Paper
DOI: 10.1039/B212313B
Citation: Green Chem., 2003,5, 118-122
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    Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(III) ligands in supercritical CO2 and CH2Cl2

    D. J. Adams, W. Chen, E. G. Hope, S. Lange, A. M. Stuart, A. West and J. Xiao, Green Chem., 2003, 5, 118
    DOI: 10.1039/B212313B

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