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Issue 71, 2003

Structural relationship of two coordination polymers of Cu(I) with the ligand ethanediyl bis(isonicotinate)

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Abstract

The flexible ligand ethanediyl bis(isonicotinate), L, is used as linking unit for Cu(I) ions in a coordination polymer. Two different structures of one-dimensional chains can be obtained, mainly depending on the co-crystallising solvent. Weak interactions such as hydrogen bonding and pi–stacking, and the exclusion of solvent molecules are responsible for the slow transformation of one compound into the other in the mother liquor.

Graphical abstract: Structural relationship of two coordination polymers of Cu(i) with the ligand ethanediyl bis(isonicotinate)

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Publication details

The article was received on 06 Aug 2003, accepted on 16 Oct 2003 and first published on 29 Oct 2003


Article type: Paper
DOI: 10.1039/B309410C
Citation: CrystEngComm, 2003,5, 405-410
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    Structural relationship of two coordination polymers of Cu(I) with the ligand ethanediyl bis(isonicotinate)

    A. Y. Robin, K. M. Fromm, H. Goesmann and G. Bernardinelli, CrystEngComm, 2003, 5, 405
    DOI: 10.1039/B309410C

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