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Issue 23, 2003
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Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent

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Abstract

Aromatic C–H borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane was catalyzed by an iridium complex generated from ½[Ir(OMe)(COD)]2 and 4,4′-di-tert-butyl-2,2′-bipyridine at room temperature in hexane and afforded the corresponding aryl- and heteroarylboronates in high yields with excellent regioselectivities.

Graphical abstract: Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent

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Publication details

The article was received on 12 Sep 2003, accepted on 08 Oct 2003 and first published on 22 Oct 2003


Article type: Communication
DOI: 10.1039/B311103B
Citation: Chem. Commun., 2003,0, 2924-2925
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    Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent

    T. Ishiyama, Y. Nobuta, J. F. Hartwig and N. Miyaura, Chem. Commun., 2003, 0, 2924
    DOI: 10.1039/B311103B

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