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Issue 17, 2003
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[V(η5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms

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Abstract

The bimetallic complex [V(Cp)]2Pn, containing a V–V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.

Graphical abstract: [V(η5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms

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Publication details

The article was received on 12 Jun 2003, accepted on 11 Jul 2003 and first published on 29 Jul 2003


Article type: Communication
DOI: 10.1039/B306688F
Citation: Chem. Commun., 2003, 2208-2209
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    [V(η5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms

    S. C. Jones and D. O'Hare, Chem. Commun., 2003, 2208
    DOI: 10.1039/B306688F

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