Issue 17, 2003
From the journal:

Chemical Communications

[V(η5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms

Simon C. Jonesa  and  Dermot O'Hare*a  

* Corresponding authors

a Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK

Abstract

The bimetallic complex [V(Cp)]2Pn, containing a V–V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.

Graphical abstract: [V(η5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms

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Article information

DOI
https://doi.org/10.1039/B306688F
Article type
Communication
Submitted
12 Jun 2003
Accepted
11 Jul 2003
First published
29 Jul 2003

Chem. Commun., 2003, 2208-2209

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[V(η5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms

S. C. Jones and D. O'Hare, Chem. Commun., 2003, 2208 DOI: 10.1039/B306688F

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