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Issue 14, 2003
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Reversible formation of excited states in intramolecular donor assisted chemiluminescence reactions of dioxetanes

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Abstract

Data are presented requiring that the currently accepted CIEEL mechanism for the chemiluminescence of electron donor substituted dioxetanes be modified to include reversible thermal population of a dioxetane excited charge transfer state that undergoes ring scission with excited product formation which is accelerated by energy acceptors.

Graphical abstract: Reversible formation of excited states in intramolecular donor assisted chemiluminescence reactions of dioxetanes

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Publication details

The article was received on 16 Apr 2003, accepted on 28 May 2003 and first published on 16 Jun 2003


Article type: Communication
DOI: 10.1039/B304245F
Citation: Chem. Commun., 2003,0, 1756-1757
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    Reversible formation of excited states in intramolecular donor assisted chemiluminescence reactions of dioxetanes

    S. Singh and E. F. Ullman, Chem. Commun., 2003, 0, 1756
    DOI: 10.1039/B304245F

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