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Issue 15, 2003
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Nonenzymatic peptide-based catalytic asymmetric phosphorylation of inositol derivatives

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Abstract

The ability to use small peptides as catalysts for asymmetric phosphorylation provides opportunities for rapid syntheses of phosphate-containing compounds and natural products. This short review outlines the genesis of this concept and its reduction to practice in the context of concise syntheses of the enantiomeric D-I-1P and D-I-3P targets. The implications for the development of additional site-selective catalysts are discussed.

Graphical abstract: Nonenzymatic peptide-based catalytic asymmetric phosphorylation of inositol derivatives

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Publication details

The article was first published on 24 Jun 2003


Article type: Focus
DOI: 10.1039/B304015C
Citation: Chem. Commun., 2003,0, 1781-1785
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    Nonenzymatic peptide-based catalytic asymmetric phosphorylation of inositol derivatives

    B. R. Sculimbrene, A. J. Morgan and S. J. Miller, Chem. Commun., 2003, 0, 1781
    DOI: 10.1039/B304015C

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