Issue 11, 2003
From the journal:

Chemical Communications

Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C–H hydride abstraction into a Cu6 cluster†

Randolf D. Köhn,*a   Zhida Pan,a   Mary F. Mahona  and  Gabriele Kociok-Köhna  

* Corresponding authors

a Department of Chemistry, University of Bath, Bath, UK
E-mail: r.d.kohn@bath.ac.uk
Fax: 44 1225 386231
Tel: 44 1225 383305

Abstract

Reaction of [Cu(MeCN)4](BF4) with N,N′,N″-trimethyl-1,3,5-triazacyclohexane in CH2Cl2 leads to two Cu6 clusters containing the triazacyclohexane as a ligand to triangular Cu3 units with the abstraction and incorporation of chloride and hydride.

Graphical abstract: Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C–H hydride abstraction into a Cu6 cluster

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Article information

DOI
https://doi.org/10.1039/B302670A
Article type
Communication
Submitted
11 Mar 2003
Accepted
03 Apr 2003
First published
02 May 2003

Chem. Commun., 2003, 1272-1273

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Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C–H hydride abstraction into a Cu6 cluster

R. D. Köhn, Z. Pan, M. F. Mahon and G. Kociok-Köhn, Chem. Commun., 2003, 1272 DOI: 10.1039/B302670A

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