Issue 11, 2003
From the journal:

Chemical Communications

Dodecanuclear and octanuclear manganese rods

Euan K. Brechin,*a   Monica Soler,b   George Christou,b   Madeleine Helliwell,a   Simon J. Teatc  and  Wolfgang Wernsdorferd  

* Corresponding authors

a Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: euan.k.brechin@man.ac.uk
Tel: 0161-275-7857

b Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA

c CLRC Daresbury Laboratory, Daresbury, Cheshire, UK

d Laboratoire Louis Néel-CNRS, 38042 Grenoble, Cedex 9, France

Abstract

The reaction of the neutral triangle [Mn3O(O2CR)6(L)3] with 1,1,1-tris(hydroxymethyl)ethane (H3thme) affords novel dodecanuclear and octanuclear manganese complexes with unusual ladder-like cores built from edge-sharing triangles.

Graphical abstract: Dodecanuclear and octanuclear manganese rods

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Article information

DOI
https://doi.org/10.1039/B302057F
Article type
Communication
Submitted
21 Feb 2003
Accepted
03 Apr 2003
First published
23 Apr 2003

Chem. Commun., 2003, 1276-1277

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Dodecanuclear and octanuclear manganese rods

E. K. Brechin, M. Soler, G. Christou, M. Helliwell, S. J. Teat and W. Wernsdorfer, Chem. Commun., 2003, 1276 DOI: 10.1039/B302057F

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