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Issue 13, 2003
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Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP

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Abstract

Depending on the substituents, R1 and R2, ruthenium(II)–p-cymene complexes bearing N-heterocyclic carbene ligands are either efficient catalysts for the well-controlled atom transfer radical polymerisation of methyl methacrylate and styrene, or promote a redox-initiated free-radical process.

Graphical abstract: Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP

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Publication details

The article was received on 15 Feb 2003, accepted on 02 May 2003 and first published on 30 May 2003


Article type: Communication
DOI: 10.1039/B301733H
Citation: Chem. Commun., 2003,0, 1526-1527
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    Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP

    L. Delaude, S. Delfosse, A. Richel, A. Demonceau and A. F. Noels, Chem. Commun., 2003, 0, 1526
    DOI: 10.1039/B301733H

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