Issue 10, 2003

Synthesis of the mixed lithium–potassium–(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity

Abstract

Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its “guest” anion is intramolecularly stitched into the complex fused-ring structure of its cationic “host”.

Graphical abstract: Synthesis of the mixed lithium–potassium–(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity

Supplementary files

Article information

Article type
Communication
Submitted
04 Feb 2003
Accepted
02 Apr 2003
First published
17 Apr 2003

Chem. Commun., 2003, 1140-1141

Synthesis of the mixed lithium–potassium–(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity

G. C. Forbes, F. R. Kenley, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara and J. A. Parkinson, Chem. Commun., 2003, 1140 DOI: 10.1039/B301374J

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