Jump to main content
Jump to site search

Issue 10, 2003
Previous Article Next Article

Synthesis of the mixed lithium–potassium–(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity

Author affiliations

Abstract

Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its “guest” anion is intramolecularly stitched into the complex fused-ring structure of its cationic “host”.

Graphical abstract: Synthesis of the mixed lithium–potassium–(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 04 Feb 2003, accepted on 02 Apr 2003 and first published on 17 Apr 2003


Article type: Communication
DOI: 10.1039/B301374J
Citation: Chem. Commun., 2003, 1140-1141
  •   Request permissions

    Synthesis of the mixed lithium–potassium–(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity

    G. C. Forbes, F. R. Kenley, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara and J. A. Parkinson, Chem. Commun., 2003, 1140
    DOI: 10.1039/B301374J

Search articles by author