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Issue 7, 2003
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An unprecedented α-C–C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex

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Abstract

Structural, spectroscopic and theoretical evidence indicate that an unusual α-C–C agostic interaction is preferred over both α- and β-C–H agostic alternatives in the title compound, TpMe2NbCl(c-C3H5)(MeCCMe).

Graphical abstract: An unprecedented α-C–C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex

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Publication details

The article was received on 10 Jan 2003, accepted on 20 Feb 2003 and first published on 05 Mar 2003


Article type: Communication
DOI: 10.1039/B300324H
Citation: Chem. Commun., 2003,0, 876-877
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    An unprecedented α-C–C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex

    J. Jaffart, M. Etienne, M. Reinhold, J. E. McGrady and F. Maseras, Chem. Commun., 2003, 0, 876
    DOI: 10.1039/B300324H

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