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Issue 4, 2003
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Liquid clathrate formation in ionic liquid–aromatic mixtures

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Abstract

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate–benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2∶1 inclusion compound.

Graphical abstract: Liquid clathrate formation in ionic liquid–aromatic mixtures

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Publication details

The article was received on 21 Dec 2002, accepted on 02 Jan 2003 and first published on 21 Jan 2003


Article type: Communication
DOI: 10.1039/B212726A
Citation: Chem. Commun., 2003,0, 476-477
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    Liquid clathrate formation in ionic liquid–aromatic mixtures

    J. D. Holbrey, W. M. Reichert, M. Nieuwenhuyzen, O. Sheppard, C. Hardacre and R. D. Rogers, Chem. Commun., 2003, 0, 476
    DOI: 10.1039/B212726A

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