Issue 3, 2003
From the journal:

Chemical Communications

Enantioselective total synthesis of (−)-heliannuol A

Hidetoshi Kishuku,a   Mitsuru Shindoa  and  Kozo Shishido*a  

* Corresponding authors

a Institute for Medicinal Resources, University of Tokushima, 1-78 Sho-machi, Tokushima, Japan
E-mail: shishido@ph2.tokushima-u.ac.jp

Abstract

An efficient and enantiocontrolled total synthesis of (−)-heliannuol A has been accomplished by employing ring closing metathesis and sequential diastereoselective epoxidation and regioselective reductive cleavage of the epoxide ring.

Graphical abstract: Enantioselective total synthesis of (−)-heliannuol A

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Article information

DOI
https://doi.org/10.1039/B211227B
Article type
Communication
Submitted
14 Nov 2002
Accepted
16 Dec 2002
First published
09 Jan 2003

Chem. Commun., 2003, 350-351

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Enantioselective total synthesis of (−)-heliannuol A

H. Kishuku, M. Shindo and K. Shishido, Chem. Commun., 2003, 350 DOI: 10.1039/B211227B

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