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Issue 4, 2003
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Fluoride-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenyl moiety substituted with a methyl having an electron-withdrawing group

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Abstract

A new type of dioxetane bearing a 3-(cyanomethyl)phenyl (1a), 3-(methoxycarbonylmethyl)phenyl (1b), 3-(benzoylmethyl)phenyl (1c), or 3-[cyano(methoxycarbonyl)methyl]phenyl group (1d) decomposed through an intermediary dioxetane bearing a benzylic carbanion to afford crimson to yellow light on treatment with TBAF in DMSO.

Graphical abstract: Fluoride-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenyl moiety substituted with a methyl having an electron-withdrawing group

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Publication details

The article was received on 06 Nov 2002, accepted on 13 Jan 2003 and first published on 27 Jan 2003


Article type: Communication
DOI: 10.1039/B210857G
Citation: Chem. Commun., 2003,0, 482-483
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    Fluoride-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenyl moiety substituted with a methyl having an electron-withdrawing group

    M. Matsumoto, T. Mizuno and N. Watanabe, Chem. Commun., 2003, 0, 482
    DOI: 10.1039/B210857G

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