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Issue 9, 2003
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Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

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Abstract

Reaction of Co(NCS)2 with 1-methyl-1′-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.

Graphical abstract: Coordination polymers based on square planar Co(ii) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

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Publication details

The article was received on 23 Oct 2002, accepted on 14 Mar 2003 and first published on 02 Apr 2003


Article type: Communication
DOI: 10.1039/B210320F
Citation: Chem. Commun., 2003,0, 1036-1037
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    Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

    D. Mok Shin, I. Su Lee, Y. Keun Chung and M. Soo Lah, Chem. Commun., 2003, 0, 1036
    DOI: 10.1039/B210320F

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