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Issue 1, 2003
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A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(I)

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Abstract

The synthesis and characterisation of a thallium(I) triscarbene complex of the chelating, tripodal carbene ligand 1,3,5-{tris(3-tert-butylimidazol-2-ylideno)methyl}-2,4,6-trimethylbenzene is reported, in which the thallium ion is coordinated by three N-heterocyclic carbene donors in a distorted trigonal planar environment.

Graphical abstract: A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(i)

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Publication details

The article was received on 17 Sep 2002, accepted on 28 Oct 2002 and first published on 26 Nov 2002


Article type: Communication
DOI: 10.1039/B209071F
Citation: Chem. Commun., 2003, 24-25
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    A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(I)

    H. Nakai, Y. Tang, P. Gantzel and K. Meyer, Chem. Commun., 2003, 24
    DOI: 10.1039/B209071F

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