Issue 1, 2003
From the journal:

Chemical Communications

Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques†

Moniek Tromp,a   Jelle R. A. Sietsma,a   Jeroen A. van Bokhoven,ac   Gino P. F. van Strijdonck,b   Richard J. van Haaren,b   Ad M. J. van der Eerden,a   Piet W. N. M. van Leeuwenb  and  Diek C. Koningsberger*a  

* Corresponding authors

a Debye Institute, Dept. Inorganic Chemistry and Catalysis, P.O. Box 80083, Utrecht, The Netherlands
Fax: +31 30 251 1027
Tel: +31 30 253 7400

b Institute for Molecular Chemistry, Nieuwe Achtergracht 166, Amsterdam, The Netherlands

c Laboratory for Technical Chemistry, ETH Hönggerberg, Zurich, Switzerland

Abstract

UV-Vis, combined with ED-XAFS shows, for the first time, the evolution of inactive Pd dimers and trimers, that are a possible first stage in the deactivation process of important palladium catalysed reactions, leading to larger palladium clusters and eventually palladium black.

Graphical abstract: Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques

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Article information

DOI
https://doi.org/10.1039/B206758G
Article type
Communication
Submitted
11 Jul 2002
Accepted
01 Nov 2002
First published
05 Dec 2002

Chem. Commun., 2003, 128-129

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Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques

M. Tromp, J. R. A. Sietsma, J. A. van Bokhoven, G. P. F. van Strijdonck, R. J. van Haaren, A. M. J. van der Eerden, P. W. N. M. van Leeuwen and D. C. Koningsberger, Chem. Commun., 2003, 128 DOI: 10.1039/B206758G

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